AAAA Battery

30-second summary

AAAA Battery

An AAAA battery is one of many types of single-cell cylindrical batteries. AAAA batteries are not as common as AA or AAA batteries used in portable electronic devices, toys, and remote controls.

Several different chemistries are used in their construction. The exact terminal voltage, capacity and practical discharge rates depend on cell chemistry; however, devices designed for AAAA cells will usually only take 1.2-1.5 V unless specified by the manufacturer.

Types of AAA Batteries:

Primary Battery

Secondary Battery

AAAA battery - size, weight, applications

An electric battery is essentially a source of DC electrical energy. It converts stored chemical energy into electrical energy through an electrochemical process. This then provides a source of electromotive force to enable currents to flow in electric and electronic circuits. A typical battery consists of one or more voltaic cells. 

The fundamental principle in an electrochemical cell is spontaneous redox reactions in two electrodes separated by an electrolyte, which is a substance that is ionic conductive and electrically insulated.

AAAA batteries are small, cylindrical batteries commonly used in small electronic devices like calculators, flashlights, laser pointers, game controllers, and similar.

Like similar but larger AA and AAA batteries, AAAA batteries also come in different chemistries, offering different performances and features but also different prices.

Dimensions and Weight of AAAA Battery

The AAAA battery (usually read as quadruple-A) is 42.5 mm long and 8.3 mm in diameter. The alkaline cell weighs around 6.5 g and produces 1.5 V. This battery size is most often used in small devices such as laser pointers, LED penlights, powered computer styluses, glucose meters, and small headphone amplifiers, with Microsoft’s Surface Pen the most prominent product taking AAAA batteries. These batteries are not as popular as AAA or AA type batteries and consequently are not as commonly available.

Some models of alkaline nine-volt batteries contain six LR61 cells connected by welded tabs. These cells are similar to AAAA cells and can be used in their place in some devices, even though they are 3.5 millimeters (0.14 in) shorter.

Types of AAAA Batteries

AAAA batteries are basically divided into primary and secondary. Several different chemistries are used in their construction. The exact terminal voltage, capacity and practical discharge rates depend on cell chemistry; however, devices designed for AAAA cells will usually only take 1.2-1.5 V unless specified by the manufacturer.

Primary AAAA Battery. A primary battery or primary cell is a non-rechargeable battery that is designed to be used once discarded after use. These batteries are most commonly used in portable devices with low current drains, are used only intermittently, or are used well away from an alternative power source, such as in alarm and communication circuits where other electric power is only intermittently available. Primary cells have higher energy density than the rechargeable secondary cell, but most types of primary cells have high inner impedance and will therefore cause a big voltage drop during high discharge current, limiting the power capacity.

  • Alkaline battery.  An alkaline battery (IEC code: L) is a type of primary battery that provides direct electric current from the electrochemical reaction between zinc and manganese dioxide (MnO2) in the presence of an alkaline electrolyte. The alkaline battery gets its name because it has an alkaline electrolyte of potassium hydroxide (KOH) instead of the acidic ammonium chloride (NH4Cl) or zinc chloride (ZnCl2) electrolyte of the zinc–carbon batteries. The alkaline cell was introduced to the market in 1959 but did not become more common than the Zinc-carbon cell until around 1980.
  • Lithium metal battery. Lithium-based primary cells are batteries that have metallic lithium as an anode. They have the lowest self-discharge rate hence the longest available shelf time, up to 10 years, and in temperatures up to 70. Using an iron disulfide cathode gives a battery with a nominal voltage of 1.5 volts. This cell is used for high-performance AA batteries.
  • Zinc-carbon battery. The zinc-carbon battery, also called the Leclanché cell, is a traditional general-purpose dry cell. Zinc–carbon batteries were the first commercial dry batteries developed from the technology of the wet Leclanché cell. This battery provides a direct electric current from the electrochemical reaction between zinc and manganese dioxide (MnO2) in the presence of an electrolyte. It produces a voltage of about 1.5 volts between the zinc anode, which is typically constructed as a cylindrical container for the battery cell, and a carbon rod surrounded by the cathode that collects the current from the manganese dioxide electrode. The name “zinc-carbon” is slightly misleading as it implies that carbon is acting as the reducing agent rather than the manganese dioxide. 
  • Zinc-chloride battery. The zinc-chloride battery is a type of primary battery developed from a zinc-carbon cell. It is frequently referred to as a heavy-duty, extra-heavy-duty, super-heavy-duty, or super-extra-heavy-duty battery. Zinc-chloride cell is an improvement on the original zinc-carbon cell, using purer chemicals and giving a longer service life and steadier voltage output as it is used and offering about twice the service life of general-purpose zinc-carbon cells, or up to four times in continuous-use or high-drain applications.

Secondary AAAA Battery. Secondary batteries, also known as secondary cells, or rechargeable batteries, are batteries that can be recharged by driving electric current in the opposite direction of the discharge current. Rechargeable batteries are often more expensive, but in high-drain applications, they offer greater value as they can be reused. In low-drain applications, the service life is more important, and the self-discharge characteristics of a rechargeable battery mean that they are less suitable for use as the primary energy source. 

  • NiMH battery. A nickel-metal hydride battery, NiMH, is a secondary battery with a positive electrode made of nickel hydroxide and a negative electrode made of a metal hydride (a hydrogen-absorbing alloy). The NiMH battery was commercially introduced in 1989 and was mainly used as a power source in portable personal computers. Since then, the NiMH battery system has become very popular in electric hybrid vehicles and makes up 10% of the total market for rechargeable batteries. Compared to the NiCd battery, the NiMH provides 40 percent higher specific energy resulting in about two times higher capacity. NiMH batteries are also less affected by the memory effect.
  • NiCd battery. The nickel-cadmium battery (Ni-Cd battery) is a type of secondary battery using nickel oxide hydroxide Ni(O)(OH) as a cathode and metallic cadmium as an anode. The abbreviation Ni-Cd is derived from the chemical symbols of nickel (Ni) and cadmium (Cd). The battery has low internal impedance resulting in high power capabilities but lower energy storage capacity compared to other battery systems. It has long cycle life and capability of rapid recharge but may suffer from voltage depression or memory effect

Characteristics of AAAA Batteries

To compare and understand the capability of each battery, some important parameters are characteristic of each battery, also within a type of battery. These parameters are a reference when a battery is needed, and specific qualities are required since batteries are used in all types of devices and for infinite purposes.

Cell Voltage

The voltage of electric batteries is created by the potential difference of the materials that compose the positive and negative electrodes in the electrochemical reaction.

Alkaline batteries have an open cell voltage of about 1.5 V. A common open circuit voltage for NiMH batteries (e.g. AAA and AA) is 1.2V.

Cut-off Voltage

The cut-off voltage is the minimum allowable voltage. It is this voltage that generally defines the “empty” state of the battery.

When testing the capacity of a NiMH or NiCd battery, a cut-off voltage of 1.0 V per cell is normally used, whereas 0.9 V is normally used as the cut-off voltage of an alkaline cell.


The coulometric capacity is the total Amp-hours available when the battery is discharged at a certain discharge current from 100% SOC to the cut-off voltage.

A typical alkaline or NiMH battery in the standard “AAAA” size has about 300 (NiMH) to 500 mAh (alkaline).

C-rate of Battery

C-rate is used to express how fast a battery is discharged or charged relative to its maximum capacity. It has units h−1. A 1C rate means that the discharge current will discharge the entire battery in 1 hour.

To obtain a reasonably good capacity reading, manufacturers commonly rate alkaline and lead acid batteries at a very low 0.05C, or a 20-hour discharge.


Batteries gradually self-discharge even if not connected and delivering current. This is due to non-current-producing “side” chemical reactions that occur within the cell even when no load is applied.

One of the main advantages of alkaline batteries is that they are easy to store. They are chemically stable, and they have a very low self-discharge rate. Alkaline batteries typically lose 2 to 3 percent of their original charge per year when stored at room temperature (20–30 °C). The NiMH battery also has high self-discharge and can lose up to 20 % of its charge during the first 24 hours and thereafter 10 % per month.


Some degradation of rechargeable batteries occurs on each charge-discharge cycle. Degradation usually occurs because electrolyte migrates away from the electrodes or because active material detaches from the electrodes.

The cycle life for NiMH batteries is typically 700-1,000 life cycles.

Other Types of Batteries

The following list summarizes notable electric battery types composed of one or more electrochemical cells. Four lists are provided in the table. The first list is a battery classification by size and format. Then, the primary (non-rechargeable) and secondary (rechargeable) cell lists are lists of battery chemistry. The third list is a list of battery applications. The final list is a list of different battery voltages.

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