{"id":209102,"date":"2024-03-21T14:05:58","date_gmt":"2024-03-21T14:05:58","guid":{"rendered":"https:\/\/www.electricity-magnetism.org\/%e5%8c%96%e5%ad%a6%e3%82%b7%e3%83%95%e3%83%88%e6%96%b9%e7%a8%8b%e5%bc%8f-%e5%ae%9a%e7%be%a9%e3%80%81%e8%a8%88%e7%ae%97%e6%96%b9%e6%b3%95%e3%81%a8%e5%bf%9c%e7%94%a8\/"},"modified":"2024-05-17T15:07:14","modified_gmt":"2024-05-17T15:07:14","slug":"%e5%8c%96%e5%ad%a6%e3%82%b7%e3%83%95%e3%83%88%e6%96%b9%e7%a8%8b%e5%bc%8f-%e5%ae%9a%e7%be%a9%e3%80%81%e8%a8%88%e7%ae%97%e6%96%b9%e6%b3%95%e3%81%a8%e5%bf%9c%e7%94%a8","status":"publish","type":"post","link":"https:\/\/www.electricity-magnetism.org\/ja\/%e5%8c%96%e5%ad%a6%e3%82%b7%e3%83%95%e3%83%88%e6%96%b9%e7%a8%8b%e5%bc%8f-%e5%ae%9a%e7%be%a9%e3%80%81%e8%a8%88%e7%ae%97%e6%96%b9%e6%b3%95%e3%81%a8%e5%bf%9c%e7%94%a8\/","title":{"rendered":"\u5316\u5b66\u30b7\u30d5\u30c8\u65b9\u7a0b\u5f0f | \u5b9a\u7fa9\u3001\u8a08\u7b97\u65b9\u6cd5\u3068\u5fdc\u7528"},"content":{"rendered":"<p class=\"sidekick\">\u5316\u5b66\u30b7\u30d5\u30c8\u65b9\u7a0b\u5f0f\u306e\u5b9a\u7fa9\u3001\u8a08\u7b97\u65b9\u6cd5\u3001\u304a\u3088\u3073NMR\u30b9\u30da\u30af\u30c8\u30ed\u30b9\u30b3\u30d4\u30fc\u306b\u304a\u3051\u308b\u5206\u5b50\u69cb\u9020\u3084\u52d5\u614b\u7814\u7a76\u306a\u3069\u306e\u5e45\u5e83\u3044\u5fdc\u7528\u306b\u3064\u3044\u3066\u89e3\u8aac\u3002<\/p>\n<h2>\u5316\u5b66\u30b7\u30d5\u30c8\u65b9\u7a0b\u5f0f | \u5b9a\u7fa9\u3001\u8a08\u7b97\u65b9\u6cd5\u3068\u5fdc\u7528<\/h2>\n<p>\u5316\u5b66\u30b7\u30d5\u30c8\u65b9\u7a0b\u5f0f\u306f\u3001\u6838\u78c1\u6c17\u5171\u9cf4\uff08NMR\uff09\u30b9\u30da\u30af\u30c8\u30ed\u30b9\u30b3\u30d4\u30fc\u306b\u304a\u3044\u3066\u91cd\u8981\u306a\u6982\u5ff5\u3067\u3059\u3002NMR\u30b9\u30da\u30af\u30c8\u30ed\u30b9\u30b3\u30d4\u30fc\u306f\u3001\u9ad8\u5206\u89e3\u80fd\u306e\u5206\u5149\u6280\u8853\u3067\u3042\u308a\u3001\u5206\u5b50\u69cb\u9020\u3084\u52d5\u614b\u306e\u8a73\u7d30\u306a\u60c5\u5831\u3092\u5f97\u308b\u305f\u3081\u306b\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u3053\u306e\u6280\u8853\u306f\u7279\u306b\u5316\u5b66\u3084\u751f\u7269\u5b66\u306e\u7814\u7a76\u306b\u304a\u3044\u3066\u5e83\u304f\u5229\u7528\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u672c\u8a18\u4e8b\u3067\u306f\u3001\u5316\u5b66\u30b7\u30d5\u30c8\u306e\u5b9a\u7fa9\u3001\u8a08\u7b97\u65b9\u6cd5\u3001\u304a\u3088\u3073\u305d\u306e\u5fdc\u7528\u306b\u3064\u3044\u3066\u89e3\u8aac\u3057\u3066\u3044\u304d\u307e\u3059\u3002<\/p>\n<h2>\u5316\u5b66\u30b7\u30d5\u30c8\u306e\u5b9a\u7fa9<\/h2>\n<p>NMR\u30b9\u30da\u30af\u30c8\u30ed\u30b9\u30b3\u30d4\u30fc\u3067\u306f\u3001\u8a66\u6599\u306b\u542b\u307e\u308c\u308b\u539f\u5b50\u6838\u306e\u5171\u9cf4\u5468\u6ce2\u6570\u3092\u6e2c\u5b9a\u3057\u307e\u3059\u3002\u3053\u306e\u5171\u9cf4\u5468\u6ce2\u6570\u306f\u3001\u8a66\u6599\u5185\u306e\u5c40\u6240\u7684\u306a\u78c1\u5834\u306e\u5f71\u97ff\u3092\u53d7\u3051\u308b\u305f\u3081\u3001\u7570\u306a\u308b\u5316\u5b66\u74b0\u5883\u306b\u3042\u308b\u539f\u5b50\u6838\u306f\u7570\u306a\u308b\u5171\u9cf4\u5468\u6ce2\u6570\u3092\u6301\u3061\u307e\u3059\u3002\u3053\u306e\u7570\u306a\u308b\u5171\u9cf4\u5468\u6ce2\u6570\u306e\u5dee\u304c\u5316\u5b66\u30b7\u30d5\u30c8\uff08chemical shift\uff09\u3068\u547c\u3070\u308c\u307e\u3059\u3002<\/p>\n<p>\u5316\u5b66\u30b7\u30d5\u30c8\u306f\u901a\u5e38\u3001\u30d4\u30fc\u30af\u306e\u4f4d\u7f6e\u3068\u3057\u3066\u30b9\u30da\u30af\u30c8\u30eb\u4e0a\u306b\u8868\u793a\u3055\u308c\u3001\u5358\u4f4d\u306fppm\uff08parts per million\uff09\u3067\u8868\u3055\u308c\u307e\u3059\u3002\u5316\u5b66\u30b7\u30d5\u30c8\u306e\u57fa\u6e96\u3068\u3057\u3066\u306f\u3001\u30c6\u30c8\u30e9\u30e1\u30c1\u30eb\u30b7\u30e9\u30f3\uff08TMS\uff09\u304c\u4e00\u822c\u7684\u306b\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002<\/p>\n<h2>\u5316\u5b66\u30b7\u30d5\u30c8\u65b9\u7a0b\u5f0f\u306e\u8a08\u7b97\u65b9\u6cd5<\/h2>\n<p>\u5316\u5b66\u30b7\u30d5\u30c8 \\( \\delta \\) \u306f\u3001\u6b21\u306e\u3088\u3046\u306b\u8a08\u7b97\u3055\u308c\u307e\u3059\uff1a<\/p>\n<pre><code> \n\\[\n\\delta = \\frac{\\nu_{\\text{sample}} - \\nu_{\\text{reference}}}{\\nu_{\\text{reference}}} \\times 10^6\n\\]\n<\/code><\/pre>\n<p>\u3053\u3053\u3067\u3001<\/p>\n<ul>\n<li>\\( \\delta \\) \u306f\u5316\u5b66\u30b7\u30d5\u30c8\uff08ppm\uff09<\/li>\n<li>\\( \\nu_{\\text{sample}} \\) \u306f\u8a66\u6599\u306e\u5171\u9cf4\u5468\u6ce2\u6570<\/li>\n<li>\\( \\nu_{\\text{reference}} \\) \u306f\u57fa\u6e96\u7269\u8cea\u306e\u5171\u9cf4\u5468\u6ce2\u6570\uff08\u4e00\u822c\u7684\u306b\u306fTMS\uff09<\/li>\n<\/ul>\n<p>\u3053\u306e\u65b9\u7a0b\u5f0f\u306b\u3088\u308a\u3001\u8a66\u6599\u4e2d\u306e\u7570\u306a\u308b\u6838\u306e\u5316\u5b66\u74b0\u5883\u306b\u57fa\u3065\u3044\u3066\u5316\u5b66\u30b7\u30d5\u30c8\u3092\u8a08\u7b97\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002<\/p>\n<h2>\u5316\u5b66\u30b7\u30d5\u30c8\u306e\u5fdc\u7528<\/h2>\n<p>\u5316\u5b66\u30b7\u30d5\u30c8\u306f\u3001NMR\u30b9\u30da\u30af\u30c8\u30ed\u30b9\u30b3\u30d4\u30fc\u306b\u304a\u3044\u3066\u591a\u304f\u306e\u91cd\u8981\u306a\u5fdc\u7528\u304c\u3042\u308a\u307e\u3059\u3002\u4ee5\u4e0b\u306f\u305d\u306e\u4e00\u90e8\u3067\u3059\uff1a<\/p>\n<ul>\n<li><strong>\u5206\u5b50\u69cb\u9020\u306e\u6c7a\u5b9a\uff1a<\/strong>\u5316\u5b66\u30b7\u30d5\u30c8\u306f\u3001\u5206\u5b50\u5185\u306e\u539f\u5b50\u306e\u4f4d\u7f6e\u95a2\u4fc2\u3084\u7d50\u5408\u72b6\u614b\u306b\u95a2\u3059\u308b\u60c5\u5831\u3092\u63d0\u4f9b\u3057\u307e\u3059\u3002\u3053\u308c\u306b\u3088\u308a\u3001\u5206\u5b50\u69cb\u9020\u306e\u63a8\u5b9a\u3084\u78ba\u8a8d\u304c\u884c\u3048\u307e\u3059\u3002<\/li>\n<li><strong>\u52d5\u614b\u7814\u7a76\uff1a<\/strong>\u5316\u5b66\u30b7\u30d5\u30c8\u3092\u5229\u7528\u3059\u308b\u3053\u3068\u3067\u3001\u5206\u5b50\u306e\u52d5\u614b\u3084\u76f8\u4e92\u4f5c\u7528\u306e\u30e1\u30ab\u30cb\u30ba\u30e0\u3092\u89e3\u6790\u3059\u308b\u3053\u3068\u304c\u53ef\u80fd\u3067\u3059\u3002\u3053\u308c\u306b\u3088\u308a\u3001\u751f\u4f53\u9ad8\u5206\u5b50\u306e\u6a5f\u80fd\u89e3\u660e\u306a\u3069\u304c\u9032\u3081\u3089\u308c\u307e\u3059\u3002<\/li>\n<li><strong>\u7d44\u6210\u5206\u6790\uff1a<\/strong>\u6df7\u5408\u7269\u306eNMR\u30b9\u30da\u30af\u30c8\u30eb\u3092\u89e3\u6790\u3059\u308b\u3053\u3068\u3067\u3001\u5404\u6210\u5206\u306e\u5316\u5b66\u30b7\u30d5\u30c8\u3092\u7279\u5b9a\u3057\u3001\u7d44\u6210\u5206\u6790\u3092\u884c\u3046\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002<\/li>\n<\/ul>\n<h2>\u307e\u3068\u3081<\/h2>\n<p>\u5316\u5b66\u30b7\u30d5\u30c8\u65b9\u7a0b\u5f0f\u306fNMR\u30b9\u30da\u30af\u30c8\u30ed\u30b9\u30b3\u30d4\u30fc\u306e\u57fa\u790e\u3068\u306a\u308b\u91cd\u8981\u306a\u6982\u5ff5\u3067\u3042\u308a\u3001\u5206\u5b50\u69cb\u9020\u306e\u89e3\u660e\u3084\u52d5\u614b\u7814\u7a76\u306b\u8cb4\u91cd\u306a\u60c5\u5831\u3092\u63d0\u4f9b\u3057\u307e\u3059\u3002\u5316\u5b66\u30b7\u30d5\u30c8\u306e\u8a08\u7b97\u65b9\u6cd5\u3068\u305d\u306e\u5fdc\u7528\u306b\u3064\u3044\u3066\u7406\u89e3\u3059\u308b\u3053\u3068\u3067\u3001\u3053\u306e\u9ad8\u5ea6\u306a\u5206\u5149\u6280\u8853\u3092\u52b9\u679c\u7684\u306b\u6d3b\u7528\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u305c\u3072NMR\u30b9\u30da\u30af\u30c8\u30ed\u30b9\u30b3\u30d4\u30fc\u306b\u8208\u5473\u3092\u6301\u3061\u3001\u3055\u3089\u306a\u308b\u7814\u7a76\u3084\u5b66\u7fd2\u3092\u9032\u3081\u3066\u307f\u3066\u304f\u3060\u3055\u3044\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5316\u5b66\u30b7\u30d5\u30c8\u65b9\u7a0b\u5f0f\u306e\u5b9a\u7fa9\u3001\u8a08\u7b97\u65b9\u6cd5\u3001\u304a\u3088\u3073NMR\u30b9\u30da\u30af\u30c8\u30ed\u30b9\u30b3\u30d4\u30fc\u306b\u304a\u3051\u308b\u5206\u5b50\u69cb\u9020\u3084\u52d5\u614b\u7814\u7a76\u306a\u3069\u306e\u5e45\u5e83\u3044\u5fdc\u7528\u306b\u3064\u3044\u3066\u89e3\u8aac\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_generate-full-width-content":"","footnotes":""},"categories":[96],"tags":[97],"class_list":["post-209102","post","type-post","status-publish","format-standard","hentry","category-96","tag-97","generate-columns","tablet-grid-50","mobile-grid-100","grid-parent","grid-50"],"yoast_head":"<!-- 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